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Aromatic compounds bearing a number of potent electron-withdrawing substituents in addition to a leaving group can occasionally endure nucleophilic substitution rather than electrophilic substitution. The typical mechanisms of $mathrm S _ mathrm N 2$ and $mathrm S _ mathrm N one$ reactions are impossible due to the $s p^ 2 $ -hybridization on the carbons of a benzene ring, but a mechanism that includes nucleophilic addition followed by elimination, referred to as $S_ mathrm N mathrm Ar $ (nucleophilic aromatic substitution), is possible.
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The Grignard reagent is never isolated. It truly is formed in Answer and applied promptly in the desired reaction. The alkylmetal bond is extremely polar, Along with the partial adverse demand about the $mathrm C $ atom, that makes the C atom really nucleophilic.
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